Issue 3, 2007
From the journal:

Chemical Communications

Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates†

Motoi Kawatsura,*a   Fumio Ata,a   Shohei Wada,a   Shuichi Hayase,a   Hidemitsu Unob  and  Toshiyuki Itoh*a  

* Corresponding authors

a Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, Japan
E-mail: kawatsur@chem.tottori-u.ac.jp, titoh@chem.tottori-uac.jp
Fax: +81 857 31 5179
Tel: +81 857 31 5179

b Integrated Center for Science, Ehime University, Matsuyama Ehime, Japan

Abstract

The regioselectivity in the ruthenium-catalysed allylic alkylation of mono substituted allyl acetates with the malonate anion was highly controlled by Ru3(CO)12 with 2-(diphenylphosphino)benzoic acid, and the linear-type alkylated product was obtained.

Graphical abstract: Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B614015G
Article type
Communication
Submitted
26 Sep 2006
Accepted
17 Oct 2006
First published
27 Oct 2006

Chem. Commun., 2007, 298-300

Permissions

Request permissions

Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates

M. Kawatsura, F. Ata, S. Wada, S. Hayase, H. Uno and T. Itoh, Chem. Commun., 2007, 298 DOI: 10.1039/B614015G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements