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Issue 10, 2007
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A one-pot synthesis of a paramagnetic high-nuclearity nickel(ii) cluster: an octadecanuclear NiII16NaI2 metal aggregate

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Abstract

An unusual NiII16NaI2 cluster which features formate as a bridging clamp between two octanuclear nickel cages is reported; preliminary magnetic studies exhibit paramagnetic low-lying states resulting from dominating antiferromagnetic interactions between the nickel(II) centers.

Graphical abstract: A one-pot synthesis of a paramagnetic high-nuclearity nickel(ii) cluster: an octadecanuclear NiII16NaI2 metal aggregate

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Article information


Submitted
21 Sep 2006
Accepted
27 Nov 2006
First published
14 Dec 2006

Chem. Commun., 2007, 1059-1061
Article type
Communication

A one-pot synthesis of a paramagnetic high-nuclearity nickel(II) cluster: an octadecanuclear NiII16NaI2 metal aggregate

B. Biswas, S. Khanra, T. Weyhermüller and P. Chaudhuri, Chem. Commun., 2007, 1059
DOI: 10.1039/B613782B

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