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Issue 5, 2007
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Catalytic asymmetric synthesis of mycocerosic acid

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Abstract

The first catalytic asymmetric total synthesis of mycocerosic acid was achieved via the application of iterative enantioselective 1,4-addition reactions and allows for the efficient construction of 1,3-polymethyl arrays with full stereocontrol; further exemplified by the synthesis of tetramethyl-decanoic acid, a component of the preen-gland wax of the graylag goose, Anser anser.

Graphical abstract: Catalytic asymmetric synthesis of mycocerosic acid

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Publication details

The article was received on 01 Sep 2006, accepted on 06 Oct 2006 and first published on 06 Nov 2006


Article type: Communication
DOI: 10.1039/B612593J
Citation: Chem. Commun., 2007,0, 489-491
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    Catalytic asymmetric synthesis of mycocerosic acid

    B. ter Horst, B. L. Feringa and A. J. Minnaard, Chem. Commun., 2007, 0, 489
    DOI: 10.1039/B612593J

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