Issue 3, 2007
From the journal:

Chemical Communications

Rhodium(i) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks†

Hiromichi Sato,a   Tetsuaki Fujihara,a   Yasushi Obora,a   Makoto Tokunaga,a   Junya Kiyosua  and  Yasushi Tsuji*a  

* Corresponding authors

a Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, and CREST, Japan Science and Technology Agency (JST), Kyoto 615-8510, Japan and Catalysis Research Center and Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Japan
E-mail: ytsuji@scl.kyoto-u.ac.jp
Fax: +81-75-383-2514

Abstract

Novel rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks were synthesized and the complexes were used as catalysts in rhodium-catalyzed hydrosilylation of α,β-unsaturated ketones to show high 1,4-adduct selectivity.

Graphical abstract: Rhodium(i) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B612385F
Article type
Communication
Submitted
30 Aug 2006
Accepted
29 Sep 2006
First published
25 Oct 2006

Chem. Commun., 2007, 269-271

Permissions

Request permissions

Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks

H. Sato, T. Fujihara, Y. Obora, M. Tokunaga, J. Kiyosu and Y. Tsuji, Chem. Commun., 2007, 269 DOI: 10.1039/B612385F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements