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Issue 22, 2007
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Stable organic azides based on rigid tetrahedral methane and adamantane structures as high energetic materials

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Abstract

A four-folded azidation of tetrakis(4-iodophenyl)methane and -adamantane leads to stable organic azides, but yet energetic materials, measured by differential scanning calorimetry (DSC). The rigid and symmetrical structures can be useful for new polymer and nanomaterial developments in material sciences as well as bioconjugations, after 1,3-dipolar cycloaddition reactions with terminal alkynes to 1,2,3-triazoles.

Graphical abstract: Stable organic azides based on rigid tetrahedral methane and adamantane structures as high energetic materials

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Publication details

The article was received on 07 Sep 2007, accepted on 20 Sep 2007 and first published on 05 Oct 2007


Article type: Communication
DOI: 10.1039/B713792C
Org. Biomol. Chem., 2007,5, 3586-3588

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    Stable organic azides based on rigid tetrahedral methane and adamantane structures as high energetic materials

    C. I. Schilling and S. Bräse, Org. Biomol. Chem., 2007, 5, 3586
    DOI: 10.1039/B713792C

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