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Issue 7, 2007
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Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

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Abstract

Rh(I)–catalysed [2 + 2 + 2] cycloaddition allows the synthesis of aryl ethers and diaryl methanes containing a high degree of steric hindrance from relatively simple diyne and alkyne precursors. The diarylmethanes made in this way show no evidence in their NMR spectra, however, of rotational restriction.

Graphical abstract: Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

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Supplementary files

Article information


Submitted
09 Jan 2007
Accepted
13 Feb 2007
First published
27 Feb 2007

Org. Biomol. Chem., 2007,5, 1028-1030
Article type
Communication

Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

J. Clayden and W. J. Moran, Org. Biomol. Chem., 2007, 5, 1028
DOI: 10.1039/B700353F

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