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Issue 5, 2007
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The application of bis(oxazoline) ligands in the catalytic enantioselective methallylation of aldehydes

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Abstract

A series of symmetric and non-symmetric bis(oxazoline) ligands were applied in the Nozaki–Hiyama–Kishi methallylation of a range of aromatic and aliphatic aldehydes. A non-symmetrical ligand with tert-butyl/benzyl-substituted oxazolines provided the highest enantioselectivity of 99.5% for the methallylation of benzaldehyde.

Graphical abstract: The application of bis(oxazoline) ligands in the catalytic enantioselective methallylation of aldehydes

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Article information


Submitted
19 Dec 2006
Accepted
15 Jan 2007
First published
26 Jan 2007

Org. Biomol. Chem., 2007,5, 763-766
Article type
Communication

The application of bis(oxazoline) ligands in the catalytic enantioselective methallylation of aldehydes

G. C. Hargaden, H. A. McManus, P. G. Cozzi and P. J. Guiry, Org. Biomol. Chem., 2007, 5, 763
DOI: 10.1039/B618516A

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