Jump to main content
Jump to site search

Issue 45, 2007
Previous Article Next Article

High-nuclearity 3d–4f [FeIII5LnIII8] complexes: synthesis, structure and magnetic properties

Author affiliations

Abstract

The isostructural tridecanuclear mixed-metal [FeIII5LnIII8] (Ln = Pr, Nd, Gd) aggregates are the largest [Fe–Ln] clusters reported to date and the magnetic properties suggest a ferrimagnetic arrangement in [Fe5Pr8] and [Fe5Nd8], whereas for [Fe5Gd8] ferromagnetic interactions are dominant leading to a large spin ground state.

Graphical abstract: High-nuclearity 3d–4f [FeIII5LnIII8] complexes: synthesis, structure and magnetic properties

Back to tab navigation

Supplementary files

Article information


Submitted
21 Sep 2007
Accepted
21 Sep 2007
First published
08 Oct 2007

Dalton Trans., 2007, 5245-5247
Article type
Communication

High-nuclearity 3d–4f [FeIII5LnIII8] complexes: synthesis, structure and magnetic properties

A. M. Ako, V. Mereacre, R. Clérac, I. J. Hewitt, Y. Lan, C. E. Anson and A. K. Powell, Dalton Trans., 2007, 5245
DOI: 10.1039/B714620P

Social activity

Search articles by author

Spotlight

Advertisements