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Issue 37, 2007
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Heterobimetallic coordination networks based on metallaporphyrins bearing four pyridine N-oxide groups as coordinating sites

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Abstract

The combination of two metallaporphyrin based tectons bearing four pyridyl-N-oxide groups with HgBr2 or PbI2 complexes leads to the formation of 3-D heterobimetallic coordination networks which were characterised in the crystalline phase by X-ray diffraction on single crystals. Both lone pairs of the oxygen atom of the pyridyl-N-oxide group participate in either coordination to the metal centre or in establishment of H-bonds with protic solvents.

Graphical abstract: Heterobimetallic coordination networks based on metallaporphyrins bearing four pyridine N-oxide groups as coordinating sites

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Publication details

The article was received on 01 Jun 2007, accepted on 06 Jul 2007 and first published on 30 Jul 2007


Article type: Paper
DOI: 10.1039/B708302E
Dalton Trans., 2007, 4126-4131

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    Heterobimetallic coordination networks based on metallaporphyrins bearing four pyridine N-oxide groups as coordinating sites

    E. Deiters, V. Bulach and M. W. Hosseini, Dalton Trans., 2007, 4126
    DOI: 10.1039/B708302E

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