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Issue 18, 2007
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[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex

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Abstract

Reaction of [Ir(PPh3)2(COD)][BArF4] with H2 in dichloroethane solution results in [Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4], which has been fully characterised by X-ray crystallography, NMR spectroscopy and ESI-MS. Its activity towards alkene hydrogenation has been compared with analogous CH2Cl2 complexes.

Graphical abstract: [Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex

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Supplementary files

Article information


Submitted
15 Feb 2007
Accepted
13 Mar 2007
First published
26 Mar 2007

Dalton Trans., 2007, 1759-1761
Article type
Communication

[Ir(PPh3)2(H)2(ClCH2CH2Cl)][BArF4]: a well characterised transition metal dichloroethane complex

G. L. Moxham, S. K. Brayshaw and A. S. Weller, Dalton Trans., 2007, 1759
DOI: 10.1039/B702399E

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