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Issue 2, 2007
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Multicoordinate ligands for actinide/lanthanide separations

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Abstract

In nuclear waste treatment processes there is a need for improved ligands for the separation of actinides (An(III)) and lanthanides (Ln(III)). Several research groups are involved in the design and synthesis of new An(III) ligands and in the confinement of these and existing An(III) ligands onto molecular platforms giving multicoordinate ligands. The preorganization of ligands considerably improves the An(III) extraction properties, which are largely dependent on the solubility and rigidity of the platform. This tutorial review summarizes the most important An(III) ligands with emphasis on the preorganization strategy using (macrocyclic) platforms.

Graphical abstract: Multicoordinate ligands for actinide/lanthanide separations

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Article information


Submitted
20 Jul 2006
First published
12 Oct 2006

Chem. Soc. Rev., 2007,36, 367-377
Article type
Tutorial Review

Multicoordinate ligands for actinide/lanthanide separations

H. H. Dam, D. N. Reinhoudt and W. Verboom, Chem. Soc. Rev., 2007, 36, 367
DOI: 10.1039/B603847F

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