Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 37, 2007
Previous Article Next Article

Rate coefficients of H-atom abstraction from ethers and isomerization of alkoxyalkylperoxy radicals

Author affiliations

Abstract

Group rate expressions for the hydrogen(H)-atom abstraction reactions from ethers by hydrogen atoms and hydroxyl(OH) radicals and the intramolecular hydrogen-transfer isomerization reactions of alkoxyalkylperoxy radicals, which result from the H-abstraction from ethers followed by the addition of O2, have been evaluated based on the quantum chemical calculations and experimental data. With the relative method proposed in the present study, it was shown that the rate coefficients of the reactions, for which only poor experimental information is available, can be reliably evaluated by calculating and extracting the difference from the well-established reactions of alkane hydrocarbons. The major features on the H-abstraction reactions from O-adjacent sites of ethers compared to those from alkanes were the suppression of the activation energy due to the decrease of the C–H bond dissociation energy and non-next neighbor substituent effect from the alkyl group on the counter side of –O–. For the hydrogen transfer isomerization reactions, similar suppression of the activation energy as well as the change in the ring strain energy was found as a major feature.

Graphical abstract: Rate coefficients of H-atom abstraction from ethers and isomerization of alkoxyalkylperoxy radicals

Back to tab navigation

Supplementary files

Article information


Submitted
27 Apr 2007
Accepted
02 Jul 2007
First published
30 Jul 2007

Phys. Chem. Chem. Phys., 2007,9, 5133-5142
Article type
Paper

Rate coefficients of H-atom abstraction from ethers and isomerization of alkoxyalkylperoxy radicals

T. Ogura, A. Miyoshi and M. Koshi, Phys. Chem. Chem. Phys., 2007, 9, 5133
DOI: 10.1039/B706388A

Social activity

Search articles by author

Spotlight

Advertisements