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Issue 28, 2007
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Electroless deposition of metallic silver from a choline chloride-based ionic liquid: a study using acoustic impedance spectroscopy, SEM and atomic force microscopy

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Abstract

In this paper, we describe the first example of a sustained galvanic coating deposited on a surface from a non-aqueous liquid. We present the surface characterization of electroless silver deposits on copper substrates from a solution of Ag+ ions in an ionic liquid based on a choline chloride (ChCl) eutectic. Through a study of these deposits and the mechanism of formation using acoustic impedance spectroscopy (QCM), probe microscopy (AFM) and electron microscopy (SEM/EDX), we demonstrate that sustained growth of the silver deposit is facilitated by the porous nature of the silver. This is in contrast to the dip-coating reaction of silver ions in aqueous media, where the reaction stops when surface coverage is reached. Electroless silver deposits of up to several microns have been obtained by dip coating in ionic liquids without the use of catalysts of strong inorganic acids.

Graphical abstract: Electroless deposition of metallic silver from a choline chloride-based ionic liquid: a study using acoustic impedance spectroscopy, SEM and atomic force microscopy

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Publication details

The article was received on 15 Mar 2007, accepted on 03 May 2007 and first published on 22 May 2007


Article type: Paper
DOI: 10.1039/B703954A
Phys. Chem. Chem. Phys., 2007,9, 3735-3743

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    Electroless deposition of metallic silver from a choline chloride-based ionic liquid: a study using acoustic impedance spectroscopy, SEM and atomic force microscopy

    A. P. Abbott, S. Nandhra, S. Postlethwaite, E. L. Smith and K. S. Ryder, Phys. Chem. Chem. Phys., 2007, 9, 3735
    DOI: 10.1039/B703954A

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