Metallic molecular crystals containing chiral or racemic guest molecules

Lee Martin; Peter Day; Hiroki Akutsu; Jun-ichi Yamada; Shin'ichi Nakatsuji; William Clegg; Ross W. Harrington; Peter N. Horton; Michael B. Hursthouse; Paul McMillan; Steven Firth

doi:10.1039/B709558A

Metallic molecular crystals containing chiral or racemic guest molecules†

Lee Martin,^a Peter Day,*^a Hiroki Akutsu,^b Jun-ichi Yamada,^b Shin'ichi Nakatsuji,^b William Clegg,^c Ross W. Harrington,^c Peter N. Horton,^d Michael B. Hursthouse,^d Paul McMillan^e and Steven Firth^e

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* Corresponding authors

^a Davy-Faraday Research Laboratory, The Royal Institution of Great Britain, 21 Albemarle Street, London, UK
E-mail: pday@ri.ac.uk
Fax: +44 (0)20 7670 2958
Tel: +44 (0)20 7409 2992

^b Graduate School of Material Science, University of Hyogo, Kamigori-cho, Ako-gun, Hyogo, Japan

^c School of Natural Sciences (Chemistry), Newcastle University, Newcastle upon Tyne, UK

^d Department of Chemistry, University of Southampton, Highfield, Southampton, UK

^e Department of Chemistry, Materials Chemistry Centre, Christopher Ingold Laboratories, University College London, 20 Gordon Street, UK

Abstract

Metallic charge-transfer salts of BEDT-TTF containing both racemic (R/S)- and chiral (S)-sec-phenethyl alcohol as guest molecules have been crystallised and their structures and physical properties are compared.

This article is part of the themed collection: In memory of Peter Day

CrystEngComm

Metallic molecular crystals containing chiral or racemic guest molecules†

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Metallic molecular crystals containing chiral or racemic guest molecules

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