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Issue 38, 2007
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Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation

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Abstract

The site-selective modification of peptides containing dehydroalanine, tyrosine and tryptophan residues has been achieved using rhodium catalysed conjugate additions or palladium catalysed aryl-amination and -etherification reactions.

Graphical abstract: Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation

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Publication details

The article was received on 27 Jul 2007, accepted on 03 Aug 2007 and first published on 15 Aug 2007


Article type: Communication
DOI: 10.1039/B711533D
Chem. Commun., 2007, 3903-3905

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    Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation

    C. J. Chapman, A. Matsuno, C. G. Frost and M. C. Willis, Chem. Commun., 2007, 3903
    DOI: 10.1039/B711533D

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