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Issue 48, 2007
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An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule

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Abstract

Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeLB5(NCS)2trans-[FeLB5(NCS)2]}·CH3OH, 1, (LB5 = N,N′-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine); the synthesis, X-ray structure, and magnetic and Mössbauer study of this unique example of co-crystallised geometric, conformational and electronic isomers are reported.

Graphical abstract: An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule

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Publication details

The article was received on 13 Jul 2007, accepted on 21 Sep 2007 and first published on 09 Oct 2007


Article type: Communication
DOI: 10.1039/B710734J
Chem. Commun., 2007, 5223-5225

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    An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule

    N. Bréfuel, C. Duhayon, S. Shova and J. Tuchagues, Chem. Commun., 2007, 5223
    DOI: 10.1039/B710734J

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