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Issue 44, 2007
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Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

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Abstract

Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp3 C–H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.

Graphical abstract: Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

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Article information


Submitted
12 Jul 2007
Accepted
22 Aug 2007
First published
03 Sep 2007

Chem. Commun., 2007, 4644-4646
Article type
Communication

Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source

J. D. Harden, J. V. Ruppel, G. Gao and X. P. Zhang, Chem. Commun., 2007, 4644
DOI: 10.1039/B710677G

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