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Issue 38, 2007
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Solid-phase based synthesis of jasplakinolide analogs by intramolecular azidealkyne cycloadditions

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Abstract

The synthesis of a focused library of jasplakinolide analogs with a 1,2,3-triazole in place of an E-configured double bond is described, featuring the Cu(I) catalyzed azidealkyne cycloaddition reaction as an efficient macrocyclization tool.

Graphical abstract: Solid-phase based synthesis of jasplakinolide analogs by intramolecular azide–alkyne cycloadditions

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Publication details

The article was received on 11 Jul 2007, accepted on 27 Jul 2007 and first published on 14 Aug 2007


Article type: Communication
DOI: 10.1039/B710650E
Chem. Commun., 2007, 3942-3944

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    Solid-phase based synthesis of jasplakinolide analogs by intramolecular azidealkyne cycloadditions

    T. Hu, R. Tannert, H. Arndt and H. Waldmann, Chem. Commun., 2007, 3942
    DOI: 10.1039/B710650E

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