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Issue 45, 2007
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Solid-state luminescence switching of platinum(ii) dithiooxamide complexes in the presence of hydrogen halide and amine gases

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Abstract

In the solid state, a non-luminescent platinum(II) dithiooxamide species adsorbs gaseous HCl, yielding a tight ion pair species which exhibits photoluminescence; the process is quantitatively reversed on heating or by exposing the sample to ammonia vapors.

Graphical abstract: Solid-state luminescence switching of platinum(ii) dithiooxamide complexes in the presence of hydrogen halide and amine gases

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Article information


Submitted
09 Jul 2007
Accepted
13 Aug 2007
First published
11 Sep 2007

Chem. Commun., 2007, 4740-4742
Article type
Communication

Solid-state luminescence switching of platinum(II) dithiooxamide complexes in the presence of hydrogen halide and amine gases

F. Nastasi, F. Puntoriero, N. Palmeri, S. Cavallaro, S. Campagna and S. Lanza, Chem. Commun., 2007, 4740
DOI: 10.1039/B710372G

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