Issue 43, 2007
From the journal:

Chemical Communications

Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(ii) reagent of bromobenzene†

Debashis Adhikari,a   John C. Huffmana  and  Daniel J. Mindiola*a  

* Corresponding authors

a Department of Chemistry and the Molecular Structure Center, Indiana University, Bloomington, USA
E-mail: mindiola@indiana.edu
Tel: 001-812-855-2399

Abstract

The first nickel complex bearing a boryl moiety, (PNP)Ni[B(catechol)] (PNP = N[2-P(CHMe2)2-4-methylphenyl]2−), has been prepared, structurally characterized, and analyzed by DFT; this rare species is shown to be a recyclable reagent for the borylation of bromobenzene, via an unusual cycle, by applying the ingredients catecholborane and NaBH4.

Graphical abstract: Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(ii) reagent of bromobenzene

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Article information

DOI
https://doi.org/10.1039/B709832D
Article type
Communication
Submitted
27 Jun 2007
Accepted
27 Aug 2007
First published
11 Sep 2007

Chem. Commun., 2007, 4489-4491

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Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene

D. Adhikari, J. C. Huffman and D. J. Mindiola, Chem. Commun., 2007, 4489 DOI: 10.1039/B709832D

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