Issue 34, 2007
From the journal:

Chemical Communications

A luminescent multicomponent species made of fullerene and Ir(iii) cyclometallated subunits†

Francesco Nastasi,a   Fausto Puntoriero,a   Sebastiano Campagna,*a   Stefano Schergna,b   Michele Maggini,*b   François Cardinali,c   Béatrice Delavaux-Nicotc  and  Jean-François Nierengarten*c  

* Corresponding authors

a Dept. of Inorg., Anal. & Phys. Chemistry, University of Messina, Via Sperone 31, 98166 Messina, Italy
E-mail: campagna@unime.it
Fax: 39 090 393756
Tel: +39 090 6765737

b Dipartimento di Scienze Chimiche, Universita' di Padova, Via Marzolo 1, 35131 Padova, Italy
E-mail: michele.maggini@unipd.it
Fax: +39 049 827 52 39
Tel: +39 049 827 56 62

c Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France
E-mail: jfnierengarten@lcc-toulouse.fr
Fax: +33 (0) 5 61 55 30 03
Tel: +33 (0) 5 61 33 31 51

Abstract

The first system containing a luminescent Ir(III) cyclometallated species and a functionalized C60 unit has been prepared; triplet–triplet energy transfer from the Ir-based MLCT state to the C60 triplet state occurs, leading to phosphorescence (lifetime, 4.8 ms) of the derivatized-C60 at 77 K.

Graphical abstract: A luminescent multicomponent species made of fullerene and Ir(iii) cyclometallated subunits

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Article information

DOI
https://doi.org/10.1039/B705296K
Article type
Communication
Submitted
10 Apr 2007
Accepted
09 May 2007
First published
25 May 2007

Chem. Commun., 2007, 3556-3558

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A luminescent multicomponent species made of fullerene and Ir(III) cyclometallated subunits

F. Nastasi, F. Puntoriero, S. Campagna, S. Schergna, M. Maggini, F. Cardinali, B. Delavaux-Nicot and J. Nierengarten, Chem. Commun., 2007, 3556 DOI: 10.1039/B705296K

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