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Issue 32, 2007
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Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

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Abstract

Density functional (DFT) calculations, high-temperature electron paramagnetic resonance (EPR) and transmission electron microscopy (TEM) results suggest that thermal homolysis of C59HN involves a remarkably stable intermediate C59N–C59HN˙ structure characterised by charge redistribution from a C59N˙ radical to a bonded C59HN.

Graphical abstract: Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

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Article information


Submitted
13 Mar 2007
Accepted
10 May 2007
First published
15 Jun 2007

Chem. Commun., 2007, 3386-3388
Article type
Communication

Stability, thermal homolysis and intermediate phases of solid hydroazafullerene C59HN

D. Arčon, M. Pregelj, P. Cevc, G. Rotas, G. Pagona, N. Tagmatarchis and C. Ewels, Chem. Commun., 2007, 3386
DOI: 10.1039/B703766J

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