Fluoride ion complexation by a cationic borane in aqueous solution

Min Hyung Lee; Tomohiro Agou; Junji Kobayashi; Takayuki Kawashima; François P. Gabbaï

doi:10.1039/B616814K

Fluoride ion complexation by a cationic borane in aqueous solution†

Min Hyung Lee,^a Tomohiro Agou,^b Junji Kobayashi,^b Takayuki Kawashima*^b and François P. Gabbaï*^a

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* Corresponding authors

^a Department of Chemistry, Texas A&M University, College Station, Texas, USA
E-mail: francois@tamu.edu

^b Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Japan

Abstract

The phosphonium borane [p-Mes₂B(C₆H₄)PMePh₂]⁺ complexes fluoride in water containing 10% methanol with a binding constant of 1.0(±0.1) × 10³ M⁻¹ to afford the zwitterion p-Mes₂FB(C₆H₄)PMePh₂.

Supplementary files

Publication details

The article was received on 16 Nov 2006, accepted on 20 Jan 2007 and first published on 06 Feb 2007

Article type: Communication

DOI: 10.1039/B616814K

Citation: Chem. Commun., 2007, 1133-1135

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Fluoride ion complexation by a cationic borane in aqueous solution

M. H. Lee, T. Agou, J. Kobayashi, T. Kawashima and F. P. Gabbaï, Chem. Commun., 2007, 1133
DOI: 10.1039/B616814K
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Chemical Communications

Fluoride ion complexation by a cationic borane in aqueous solution†

Abstract

Supplementary files

Publication details

Fluoride ion complexation by a cationic borane in aqueous solution

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