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Issue 8, 2007
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Twelve-connected porous metal–organic frameworks with high H2 adsorption

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Abstract

The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3n(solv)}1 and {[Fe3(O)(L)3n(solv)}2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.

Graphical abstract: Twelve-connected porous metal–organic frameworks with high H2 adsorption

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Article information


Submitted
02 Oct 2006
Accepted
02 Nov 2006
First published
07 Dec 2006

Chem. Commun., 2007, 840-842
Article type
Communication

Twelve-connected porous metal–organic frameworks with high H2 adsorption

J. Jia, X. Lin, C. Wilson, A. J. Blake, N. R. Champness, P. Hubberstey, G. Walker, E. J. Cussen and M. Schröder, Chem. Commun., 2007, 840
DOI: 10.1039/B614254K

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