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Issue 8, 2007
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Twelve-connected porous metal–organic frameworks with high H2 adsorption

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Abstract

The twelve-connected metal–organic frameworks {[Ni3(OH)(L)3n(solv)}1 and {[Fe3(O)(L)3n(solv)}2 [LH2 = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H2 up to 4.15 wt% at 77 K.

Graphical abstract: Twelve-connected porous metal–organic frameworks with high H2 adsorption

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Publication details

The article was received on 02 Oct 2006, accepted on 02 Nov 2006 and first published on 07 Dec 2006


Article type: Communication
DOI: 10.1039/B614254K
Chem. Commun., 2007, 840-842

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    Twelve-connected porous metal–organic frameworks with high H2 adsorption

    J. Jia, X. Lin, C. Wilson, A. J. Blake, N. R. Champness, P. Hubberstey, G. Walker, E. J. Cussen and M. Schröder, Chem. Commun., 2007, 840
    DOI: 10.1039/B614254K

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