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Issue 27, 2007
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Synthesis of α-keto esters by the rhodium-catalysed reaction of cyanoformate with arylboronic acids

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Abstract

An arylrhodium(I) species selectively reacts with the cyano group of ethyl cyanoformate to afford the corresponding α-keto ester in good yield.

Graphical abstract: Synthesis of α-keto esters by the rhodium-catalysed reaction of cyanoformate with arylboronic acids

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Supplementary files

Article information


Submitted
19 Mar 2007
Accepted
10 Apr 2007
First published
26 Apr 2007

Chem. Commun., 2007, 2855-2857
Article type
Communication

Synthesis of α-keto esters by the rhodium-catalysed reaction of cyanoformate with arylboronic acids

H. Shimizu and M. Murakami, Chem. Commun., 2007, 2855
DOI: 10.1039/B704105E

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