Issue 15, 2007

A ‘metallic tape’ stabilized by an unprecedented (μ522211-) scorpionate binding mode

Abstract

The Janus scorpionate ligand, tris(mercaptothiadiazolyl)borate, exhibits extraordinary coordination capacity and versatility, binding from two up to five metal cations as demonstrated by its thallium(I) salt, a compound that serves as a model for metal–surface binding.

Graphical abstract: A ‘metallic tape’ stabilized by an unprecedented (μ5-κ2,κ2,κ2,κ1,κ1-) scorpionate binding mode

Supplementary files

Article information

Article type
Communication
Submitted
18 Dec 2006
Accepted
15 Feb 2007
First published
05 Mar 2007

Chem. Commun., 2007, 1524-1526

A ‘metallic tape’ stabilized by an unprecedented (μ522211-) scorpionate binding mode

J. R. Gardinier, R. M. Silva, C. Gwengo and S. V. Lindeman, Chem. Commun., 2007, 1524 DOI: 10.1039/B618519C

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