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Abstract | Cited by

A highly diastereoselective organocatalytic synthesis of unique functionalised vinyl epoxides, displaying a Morita–Baylis–Hillman backbone, has been developed by means of an user friendly sulfonium ylide epoxidation of aldehydes from a readily available α-(bromomethyl)acrylamide derivative. The first result in the asymmetric version is discussed.

Graphical abstract: A diastereoselective and concise synthesis of functionalised vinyl epoxides with a Morita–Baylis–Hillman backbone

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