Issue 18, 2006
From the journal:

Organic & Biomolecular Chemistry

A short enantioselective total synthesis of the phytotoxic lactoneherbarumin III

Joshodeep Boruwa,a   Naminita Gogoia  and  Nabin C. Barua*a  

* Corresponding authors

a Natural Products Chemistry Division, Regional Research Laboratory (CSIR), Jorhat, Assam, India
E-mail: ncbarua2000@yahoo.co.in
Fax: +91-376-2370011

Abstract

The phytotoxic lactone herbarumin III has been synthesized in 11% overall yield. The approach applied uses Keck's asymmetric allylation and Sharpless epoxidation to build the key fragment. Esterification with 5-hexenoic acid and a ring closing metathesis was used to arrive at the target.

Graphical abstract: A short enantioselective total synthesis of the phytotoxic lactone herbarumin III

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Article information

DOI
https://doi.org/10.1039/B605982A
Article type
Paper
Submitted
26 Apr 2006
Accepted
27 Jul 2006
First published
14 Aug 2006

Org. Biomol. Chem., 2006,4, 3521-3525

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A short enantioselective total synthesis of the phytotoxic lactone herbarumin III

J. Boruwa, N. Gogoi and N. C. Barua, Org. Biomol. Chem., 2006, 4, 3521 DOI: 10.1039/B605982A

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