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Issue 7, 2006
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Asymmetric allylation of aryl aldehydes: studies on the scope and mechanism of the palladium catalysed diethylzinc mediated umpolung using phosphoramidite ligands

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Abstract

Using modular, monodentate phosphoramidite ligands, enantioselective palladium catalysed diethylzinc mediated allylation of aldehydes was achieved. The scope of the asymmetric C–C bond formation was investigated with respect to nucleophilic and electrophilic components and an alternative reaction mechanism is proposed based on our findings.

Graphical abstract: Asymmetric allylation of aryl aldehydes: studies on the scope and mechanism of the palladium catalysed diethylzinc mediated umpolung using phosphoramidite ligands

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Publication details

The article was received on 21 Dec 2005, accepted on 01 Feb 2006 and first published on 17 Feb 2006


Article type: Paper
DOI: 10.1039/B518165H
Citation: Org. Biomol. Chem., 2006,4, 1278-1283

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    Asymmetric allylation of aryl aldehydes: studies on the scope and mechanism of the palladium catalysed diethylzinc mediated umpolung using phosphoramidite ligands

    G. P. Howell, A. J. Minnaard and B. L. Feringa, Org. Biomol. Chem., 2006, 4, 1278
    DOI: 10.1039/B518165H

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