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Issue 12, 2006
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Design of tailored multi-charged phosphorus surface-block dendrimers

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Abstract

Polycationic or neutral dendrons of generation 1 to 3 bearing protonated (or not) amino end groups and a vinyl group at the focal point as well as polyanionic or neutral dendrons of generation 1 to 3 decorated with carboxylate or carboxylic groups on their surface and exhibiting a vinyl group at the core were prepared. Addition of ethylenediamine to the vinyl core of dendrons having amino end groups allowed the synthesis of uniquely tailored water-soluble phosphorus bis-dendrons via core to core assembling of dendrons having a vinyl core. In preliminary experiments layer-by-layer deposition of bis-dendrons on silica surface was demonstrated.

Graphical abstract: Design of tailored multi-charged phosphorus surface-block dendrimers

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Article information


Submitted
21 Jul 2006
Accepted
31 Aug 2006
First published
22 Sep 2006

New J. Chem., 2006,30, 1731-1736
Article type
Paper

Design of tailored multi-charged phosphorus surface-block dendrimers

V. Maraval, A. Maraval, G. Spataro, A. Caminade, J. Majoral, D. H. Kim and W. Knoll, New J. Chem., 2006, 30, 1731 DOI: 10.1039/B610632N

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