Issue 11, 2006
From the journal:

New Journal of Chemistry

Catalysed low temperature H2 release from nitrogen heterocycles

Audrey Moores,a   Macarena Poyatos,a   Yi Luo*b  and  Robert H. Crabtree*a  

* Corresponding authors

a Department of Chemistry, Yale University, 225 Prospect Street, P.O. Box 208107, New Haven, USA
E-mail: robert.crabtree@yale.edu
Fax: +1 (203) 432 6144
Tel: +1 (203) 432 8996

b Royal Institute of Technology, Department of Theoretical Chemistry, Albanova University Center, Stockholm, Sweden
E-mail: luo@kth.se
Fax: +46 8 55378590
Tel: +46 8 55378414

Abstract

In an experimental and computational study, nitrogen- and oxygen-containing heterocycles were compared with carbocycles as liquid substrates for hydrogen release with heterogeneous catalysts. Heteroatom substitution, particularly by nitrogen, favours low temperature H2 release; indoline was fully dehydrogenated in less than 30 min with Pd/C at 110 °C.

Graphical abstract: Catalysed low temperature H2 release from nitrogen heterocycles

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Article information

DOI
https://doi.org/10.1039/B608914C
Article type
Paper
Submitted
23 Jun 2006
Accepted
18 Aug 2006
First published
11 Sep 2006

New J. Chem., 2006,30, 1675-1678

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Catalysed low temperature H2 release from nitrogen heterocycles

A. Moores, M. Poyatos, Y. Luo and R. H. Crabtree, New J. Chem., 2006, 30, 1675 DOI: 10.1039/B608914C

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