This review describes recent advances in the development of thiazyl radicals, particularly dithiadiazolyl (RCNSSN) and dithiazolyl (RCSNSCR) as molecule-based materials. Particular emphasis is placed on their potential applications as molecular conductors, magnets and switchable materials and incorporates an overview of the structure–property relationships required in these molecular systems.
J. M. Rawson, A. Alberola and A. Whalley, J. Mater. Chem., 2006, 16, 2560 DOI: 10.1039/B603199D
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