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A simple, fast and inexpensive microwave-irradiated reaction permitting the synthesis of new sulfonylmethylbenzothiazoles in water by S-alkylation of 2-chloromethyl-6-nitrobenzothiazole 2 with different benzenesulfinic acid anions 3 is reported.

Graphical abstract: Rapid microwave-promoted synthesis of new sulfonylmethylbenzothiazoles in water

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