Electrical transport in saturated and conjugated molecular wires
Abstract
The mechanism for charge transport in dithio molecular wires tethered between two gold electrodes is investigated, using both a steady state and a time-dependent quantum mechanical approach. The interface with the electrodes is modeled by two gold clusters and the electronic structure of the entire Aun–S–bridge–S–Aun system is computed ab initio at the DFT level and semi-empirically, with the extended Hückel theory. Current vs. applied bias, I–V, curves are computed using a scattering Landauer-type formalism in a steady state picture. The applied source–drain and gate voltages are included at the ab initio level in the electronic Hamiltonian and found to influence strongly the I–V characteristics. The time evolution of a non stationary electronic wave packet initially localized on a gold atom at one end of the extended system shows that charge transfer proceeds sequentially, by a hopping mechanism, to the opposite end. Analysis of the effective one electron Hamiltonian