Issue 33, 2006
From the journal:

Dalton Transactions

The role of electrochemistry in the development of π-basic dearomatization agents†

Yogesh Surendranatha  and  W. Dean Harman*a  

* Corresponding authors

a The University of Virginia, Charlottesville

Abstract

Dihapto-coordination of aromatic molecules promotes numerous organic transformations that are not observed for the free aromatics. The development of osmium, rhenium, tungsten and molybdenum complexes that are capable of such binding is described in this perspective. The stability of these complexes strongly correlates to the metal d5/d6 reduction potential and electrochemical data has played a central role in their design.

Graphical abstract: The role of electrochemistry in the development of π-basic dearomatization agents

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Article information

DOI
https://doi.org/10.1039/B607694G
Article type
Perspective
Submitted
30 May 2006
Accepted
04 Jul 2006
First published
26 Jul 2006

Dalton Trans., 2006, 3957-3965

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The role of electrochemistry in the development of π-basic dearomatization agents

Y. Surendranath and W. D. Harman, Dalton Trans., 2006, 3957 DOI: 10.1039/B607694G

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