Issue 31, 2006
From the journal:

Dalton Transactions

The first complexes and cyclodimerisations of methylphosphaalkyne (P[triple bond, length as m-dash]CMe)†

Cameron Jones,*a   Christian Schultena  and  Andreas Stascha  

* Corresponding authors

a Centre for Fundamental and Applied Main Group Chemistry, School of Chemistry, Main Building, Cardiff University, Cardiff, UK
E-mail: jonesca6@cardiff.ac.uk

Abstract

The first complexes and cyclodimerisations of methylphosphaalkyne, P[triple bond, length as m-dash]CMe, are reported to arise from its reactions with a range of platinum(0) complexes and [W(CO)5(THF)]. A number of differences between the chemistry of this phosphaalkyne and that of its bulkier analogues have been highlighted and explained on steric grounds.

Graphical abstract: The first complexes and cyclodimerisations of methylphosphaalkyne (P [[triple bond, length as m-dash]] CMe)

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Article information

DOI
https://doi.org/10.1039/B607489H
Article type
Communication
Submitted
26 May 2006
Accepted
15 Jun 2006
First published
22 Jun 2006

Dalton Trans., 2006, 3733-3735

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The first complexes and cyclodimerisations of methylphosphaalkyne (P[triple bond, length as m-dash]CMe)

C. Jones, C. Schulten and A. Stasch, Dalton Trans., 2006, 3733 DOI: 10.1039/B607489H

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