Heptacoordinated MnII in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)6][Mn(CH3OH)MIII(ox)3]2 (MIII = Cr, Rh; ox = oxalate dianion; L = H2O, CH3OH)

Eugenio Coronado; José Ramón Galán-Mascarós; Carlos Martí-Gastaldo; Ana Murcia Martínez

doi:10.1039/B603504C

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Heptacoordinated Mn^II in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)₆][Mn(CH₃OH)M^III(ox)₃]₂ (M^III = Cr, Rh; ox = oxalate dianion; L = H₂O, CH₃OH)

Eugenio Coronado,*^a José Ramón Galán-Mascarós,*^a Carlos Martí-Gastaldo^a and Ana Murcia Martínez^a

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* Corresponding authors

^a Instituto de Ciencia Molecular, Universidad de Valencia, Polígono de la Coma s/n, Paterna, Spain
E-mail: jose.r.galan@uv.es, eugenio.coronado@uv.es
Fax: +34 96354 3273
Tel: +34 96354 4420

Abstract

Oxalate-based magnets have been known with several different crystallographic structures, from 1D to 3D, but with all of them based in metal ions with octahedral coordination. In this article we report a new bidimensional oxalate-bridged bimetallic magnet where the divalent metal appears heptacoordinated, which has strong effects in the structure and properties of this materials.

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Crystal structure data TXT (34K)

Article information

DOI: https://doi.org/10.1039/B603504C
Article type: Paper
Submitted: 08 Mar 2006
Accepted: 08 May 2006
First published: 15 May 2006

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Dalton Trans., 2006, 3294-3299

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Heptacoordinated Mn^II in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)₆][Mn(CH₃OH)M^III(ox)₃]₂ (M^III = Cr, Rh; ox = oxalate dianion; L = H₂O, CH₃OH)

E. Coronado, J. R. Galán-Mascarós, C. Martí-Gastaldo and A. M. Martínez, Dalton Trans., 2006, 3294 DOI: 10.1039/B603504C

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Dalton Transactions

Heptacoordinated Mn^II in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)₆][Mn(CH₃OH)M^III(ox)₃]₂ (M^III = Cr, Rh; ox = oxalate dianion; L = H₂O, CH₃OH)

Abstract

Supplementary files

Article information

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Heptacoordinated Mn^II in oxalate-based bimetallic 2D magnets: synthesis and characterisation of [Mn(L)₆][Mn(CH₃OH)M^III(ox)₃]₂ (M^III = Cr, Rh; ox = oxalate dianion; L = H₂O, CH₃OH)

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