Modified procedure for improved synthesis of some octameric silsesquioxanesvia hydrolytic polycondenzation in the presence of Amberlite ion-exchange resins

Abstract

Practical alternative procedures are described for the syntheses of octavinylsilsesquioxane 1, octaphenylsilesquioxane and octabenzylsilsesquioxane. The hydrolytic polycondensation of RSiX₃ (R = CH₂CH–, C₆H₅– or C₆H₅CH₂–; X = Cl, OCH₃, or OC₂H₅) in the presence of solid acid or base Amberlite ion-exchange resin gave improved yields of the corresponding octameric oligosilsesquioxanes. Repetitive usage of the Amberlite resin as the hydrolysis reagent was tested during synthesis of 1. The results indicate that it could be used many times in the same solvent making the procedure a more economically viable technique.