Synthesis, crystal structures and magnetic behaviour of dimeric and tetrameric gadolinium carboxylates with trichloroacetic acid†
Abstract
The novel gadolinium(III) containing compounds (CH3NH3)2[Gd2(CCl3COO)6(H2O)6](CCl3COO)2·2CCl3COOH (1) and (NH3CH3)2[Gd4(OH)4(CCl3COO)10(H2O)6]·2H2O (2) were synthesized and structurally characterized by