Electrochemical bursting oscillations on a high-dimensional slow subsystem

Abstract

Experiments are carried out with a chemical burster, the electrodissolution of iron in sulfuric acid solution. The system exhibits bursting oscillations in which fast periodic spiking is superimposed on chaotic, slow oscillations. Regularization of the slow dynamics, i.e., transition from chaotic to periodic bursting oscillations, is investigated through changes in the experimental parameters (circuit potential, external resistance, and electrode diameter). These transitions are accompanied by changes in the fast dynamics; a ‘Hopf–Hopf’ spiking is transformed to ‘homoclinic-Hopf’ spiking. The periodic bursting is destroyed through a period lengthening process in which the fast spiking region extends to a large fraction of the slow oscillatory cycle until there is no clear distinction between the fast and slow oscillations. Finally, it is shown that the time-scales of the fast spiking and, to a lesser extent, of the slow oscillations (or the occurrence of fast spiking) can be controlled with periodic perturbation of an experimental parameter, the circuit potential.