Issue 44, 2006
From the journal:

Chemical Communications

Switching catalytic reaction conducted in pore void of mesoporous material by redox gate control†

Masahiro Fujiwara,*a   Shigeki Terashima,b   Yasuko Endo,a   Kumi Shiokawaa  and  Hiroyoshi Ohueb  

* Corresponding authors

a Kansai Center, National Institute of Advanced Industrial Science and Technology (AIST), 1 Midorigaoka, Ikeda, Osaka 563-8577, Japan
E-mail: m-fujiwara@aist.go.jp.
Fax: +81 72 75 9628
Tel: +81 72 751 9652

b Osaka Institute of Technology, 5 Ohmiya, Asahi-ku, Osaka 535-8585, Japan

Abstract

A molecular gate attached on the pore outlet of a mesoporous material, which is opened and closed by redox system of thiol groups, effectively switched the progress of a catalytic reaction promoted by the acidic site in the pore void.

Graphical abstract: Switching catalytic reaction conducted in pore void of mesoporous material by redox gate control

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Article information

DOI
https://doi.org/10.1039/B610444D
Article type
Communication
Submitted
20 Jul 2006
Accepted
07 Sep 2006
First published
02 Oct 2006

Chem. Commun., 2006, 4635-4637

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Switching catalytic reaction conducted in pore void of mesoporous material by redox gate control

M. Fujiwara, S. Terashima, Y. Endo, K. Shiokawa and H. Ohue, Chem. Commun., 2006, 4635 DOI: 10.1039/B610444D

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