Issue 41, 2006
From the journal:

Chemical Communications

Nickel catalyzed Grob fragmentation: ω-dienyl aldehydes synthesis†

Masahiko Mori,b   Masanari Kimura,b   Yushi Takahashib  and  Yoshinao Tamaru*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14 Bunkyo, Nagasaki, Japan
E-mail: tamaru@net.nagasaki-u.ac.jp

b Graduate School of Science and Technology, Nagasaki University, 1-14 Bunkyo, Nagasaki, Japan

Abstract

With a proper choice of phosphane ligands, a Ni(cod)2–phosphane catalyst promotes decarboxylative ring-opening reaction of a wide structural variety of cyclic carbonates 1 to give ω-dienyl aldehydes 2 in good yields.

Graphical abstract: Nickel catalyzed Grob fragmentation: ω-dienyl aldehydes synthesis

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Article information

DOI
https://doi.org/10.1039/B610164J
Article type
Communication
Submitted
17 Jul 2006
Accepted
27 Jul 2006
First published
01 Sep 2006

Chem. Commun., 2006, 4303-4305

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Nickel catalyzed Grob fragmentation: ω-dienyl aldehydes synthesis

M. Mori, M. Kimura, Y. Takahashi and Y. Tamaru, Chem. Commun., 2006, 4303 DOI: 10.1039/B610164J

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