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Abstract | Cited by

The appropriate choice of organometallic nucleophile enables the straightforward preparation of different stereoisomers of 2-substituted pyrrolizidinones utilising the rhodium-catalysed 1,4-addition reaction.

Graphical abstract: Switching stereoselectivity in rhodium-catalysed 1,4-additions: the asymmetric synthesis of 2-substituted pyrrolizidinones

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