Mononuclear copper(ii)–hydroperoxo complex derived from reaction of copper(i) complex with dioxygen as a model of DβM and PHM†‡
Abstract
A mononuclear copper(II)–hydroperoxo species has been generated by the reaction of Cu(I)–H2BPPA complex with dioxygen, which illustrates the enzymatic reaction process of the CuB site in the DβM and PHM.