Structural/bonding insights from new geometrical varieties of two Pt–Au carbonyl/phosphine clusters, [Pt3(AuPPh3)5(μ2-CO)2L3]+ (L3 = (CO)2PPh3) and [(μ6-Au){Pt3(μ2-CO)3L4}2]+ (L = PMe3)†
Abstract
Structural/bonding considerations of two new Pt–Au clusters, [Pt3(AuPPh3)5(μ2-CO)2(CO)2PPh3]+ (1) and [(μ6-Au){Pt3(μ2-CO)3(PMe3)4}2]+ (2) isolated (as