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Issue 36, 2006
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Alkali-metal-catalyzed addition of primary and secondary phosphines to carbodiimides. A general and efficient route to substituted phosphaguanidines

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Abstract

Organo alkali metal compounds such as nBuLi and (Me3Si)2NK act as excellent catalyst precursors for the addition of phosphine P–H bonds to carbodiimides, offering a general and atom-economical route to substituted phosphaguanidines, with excellent tolerability to aromatic C–Br and C–Cl bonds.

Graphical abstract: Alkali-metal-catalyzed addition of primary and secondary phosphines to carbodiimides. A general and efficient route to substituted phosphaguanidines

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Article information


Submitted
29 Jun 2006
Accepted
18 Jul 2006
First published
02 Aug 2006

Chem. Commun., 2006, 3812-3814
Article type
Communication

Alkali-metal-catalyzed addition of primary and secondary phosphines to carbodiimides. A general and efficient route to substituted phosphaguanidines

W. Zhang, M. Nishiura and Z. Hou, Chem. Commun., 2006, 3812
DOI: 10.1039/B609198A

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