Issue 37, 2006
From the journal:

Chemical Communications

Palladium-catalyzed silylation of alcohols with hexamethyldisilane†

Eiji Shirakawa,*a   Koji Hironaka,a   Hidehito Otsukaa  and  Tamio Hayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto, Japan
E-mail: shirakawa@kuchem.kyoto-u.ac.jp
Fax: +81 75 753 3988

Abstract

The combination of hexamethyldisilane and a catalytic amount of [PdCl(η3-C3H5)]2–PPh3 was found to be effective for the trimethylsilylation of alcohols, where both of the two trimethylsilyl groups of hexamethyldisilane were transferred to alcohols without coproduction of any stoichiometric amount of byproduct but H2.

Graphical abstract: Palladium-catalyzed silylation of alcohols with hexamethyldisilane

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B608958E
Article type
Communication
Submitted
23 Jun 2006
Accepted
14 Jul 2006
First published
04 Aug 2006

Chem. Commun., 2006, 3927-3929

Permissions

Request permissions

Palladium-catalyzed silylation of alcohols with hexamethyldisilane

E. Shirakawa, K. Hironaka, H. Otsuka and T. Hayashi, Chem. Commun., 2006, 3927 DOI: 10.1039/B608958E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements