Issue 40, 2006
From the journal:

Chemical Communications

Gas-phase regiocontrolled generation of charged amino acid and peptide radicals†

Sheena Wee,a   Adam Mortimer,bc   Damian Moran,cd   Adam Wright,b   Christopher K. Barlow,ace   Richard A. J. O'Hair,*ace   Leo Radom*cd  and  Christopher J. Easton*bc  

* Corresponding authors

a School of Chemistry, University of Melbourne, Australia

b Research School of Chemistry, Australian National University, ACT, Australia

c ARC Centre of Excellence in Free Radical Chemistry and Biotechnology, Australia

d School of Chemistry, University of Sydney, Australia

e Bio21 Institute of Molecular Science and Biotechnology, University of Melbourne, Victoria, Australia

Abstract

The combined use of advanced mass spectrometry experiments, condensed-phase synthesis of serine and homoserine nitrate ester radical precursors, and high-level ab initio calculations provides a powerful way of examining the fundamental reactivity of radicals derived from peptides.

Graphical abstract: Gas-phase regiocontrolled generation of charged amino acid and peptide radicals

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Article information

DOI
https://doi.org/10.1039/B608724H
Article type
Communication
Submitted
20 Jun 2006
Accepted
07 Jul 2006
First published
29 Aug 2006

Chem. Commun., 2006, 4233-4235

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Gas-phase regiocontrolled generation of charged amino acid and peptide radicals

S. Wee, A. Mortimer, D. Moran, A. Wright, C. K. Barlow, R. A. J. O'Hair, L. Radom and C. J. Easton, Chem. Commun., 2006, 4233 DOI: 10.1039/B608724H

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