Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies†
Abstract
A bis-porphyrinic rectangle is created via a double self-assembly algorithm using two orthogonal coordination themes, i.e. first a 90° building block composed of a dynamic heteroleptic Cu(I) or Ag(I) bisphenanthroline followed by a coordinative dimerization using the