Issue 37, 2006
From the journal:

Chemical Communications

Electrochemical synthesis of cyclo[8]pyrrole

Christophe Bucher,*a   Charles H. Devillers,a   Jean-Claude Moutet,a   Jacques Pécautc  and  Jonathan L. Sessler*b  

* Corresponding authors

a Laboratoire d'Electrochimie Organique et de Photochimie Rédox, UMR CNRS 5630, Institut de Chimie Moléculaire de Grenoble, FR CNRS 2607, Université Joseph Fourier, BP 53, Grenoble Cédex 9, France
E-mail: christophe.bucher@ujf-grenoble.fr

b Department of Chemistry and Biochemistry, University of Texas, 1 University Station A5300 Austin, Texas, USA
E-mail: sessler@mail.utexas.edu

c CEA/DRMFC/SCIB, Laboratoire de Coordination et Nanochimie, 17 rue des Martyrs, Grenoble Cédex 9, France

Abstract

The utility of an electrochemical oxidative strategy in the synthesis of expanded porphyrins is demonstrated by the preparation of cyclo[8]pyrrole in high yield via a bipyrrole C(2)–C(2)′ coupling process.

Graphical abstract: Electrochemical synthesis of cyclo[8]pyrrole

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Article information

DOI
https://doi.org/10.1039/B606998C
Article type
Communication
Submitted
18 May 2006
Accepted
14 Jul 2006
First published
07 Aug 2006

Chem. Commun., 2006, 3891-3893

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Electrochemical synthesis of cyclo[8]pyrrole

C. Bucher, C. H. Devillers, J. Moutet, J. Pécaut and J. L. Sessler, Chem. Commun., 2006, 3891 DOI: 10.1039/B606998C

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